All metallic and non-metallic
coatings applied by electrolytic or electroless methods
to a foreign substrate exhibit a degree of stress that
may be compressive or tensile in nature. The degree of
stress within these coatings may be small or great. In
applications where the stress levels are high, it is
common for such coatings to crack, blister and peel away
from the substrate material. Thus, protection of the
basis material is lost and the rate of basis metal corrosion
is accelerated. High stress levels in electroformed deposits
can even cause electroforms to warp.
Internal stress as a force within metallic coatings
results from the inclusion of materials foreign to
the pure element that is being deposited. The foreign
matter becomes entrapped in the matrix and disrupts
the orderly building of the pure element atoms into
their natural lattice structure. As the natural lattice
formation is altered, the internal deposit stress increases.
This phenomenon has been recognized since the mid-1800s.
A given basis material will undergo distortion when
a coating of another material is applied to it. The
challenge for the plating industry has been two-fold:
to minimize coating stress levels and to accurately
measure coating stress values.
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