Specialty Test
   
A NEW FRONTIER FOR DEPOSIT STRESS
MEASUREMENTS
By Frank H. Leaman
Specialty Testing and Development Company, Inc.
York, PA USA
ABSTRACT
Internal stress exists as an inherent force within electroplated and chemically applied coatings, resulting from the inclusion of foreign organic and metallic contaminants. These materials disrupt the orderly building of the respective atoms according to their natural lattice structures and create internal stress. The induced stress can be tensile or compressive in nature, causing the deposit to contract or expand in relation to the basis substrate. High internal stress levels produce fractures in coatings that cause deposit flaking, blistering, peeling, and the distortion of electroformed products. These deposit failures accelerate corrosion of the substrate materials significantly. This paper discloses a new development that enables accurate deposit stress measurements at values near zero stress, whether said stress is tensile or compressive in nature. Common errors and misconceptions in regard to deposit measuring techniques are explained and fallacies concerning the interpretation of test results are also addressed. For example, electroformed nickel deposit stress is frequently being determined at much lower numbers than the actual values. Internal deposit stress values are presented for the following electroplating baths: cobalt-hardened gold, selenium brightened silver (99.9% deposit purity), semi-bright nickel sulfamate with bromide ion, semi-bright acid copper, and bright acid tin. The deposit stress tests determined in this report include the employment of the bent strip, the spiral contractometer, and the stress-meter methods.

*For more information contact:
Frank H. Leaman
Specialty Testing and Development Company, Inc.
137 Reynolds Mill Road
York, PA 17403 USA
Phone – (717) 891-4989
Email – FLeaman@specialtytest.com
Introduction and background

All metallic and non-metallic coatings applied by electrolytic or electroless methods to a foreign substrate exhibit a degree of stress that may be compressive or tensile in nature. The degree of stress within these coatings may be small or great. In applications where the stress levels are high, it is common for such coatings to crack, blister and peel away from the substrate material. Thus, protection of the basis material is lost and the rate of basis metal corrosion is accelerated. High stress levels in electroformed deposits can even cause electroforms to warp.

Internal stress as a force within metallic coatings results from the inclusion of materials foreign to the pure element that is being deposited. The foreign matter becomes entrapped in the matrix and disrupts the orderly building of the pure element atoms into their natural lattice structure. As the natural lattice formation is altered, the internal deposit stress increases. This phenomenon has been recognized since the mid-1800s. A given basis material will undergo distortion when a coating of another material is applied to it. The challenge for the plating industry has been two-fold: to minimize coating stress levels and to accurately measure coating stress values.

Methods of stress measurement
From this figure, the following equation can be derived to determine the value of coating internal stress.

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ADDRESS: 137 Reynolds Mill Road York, PA 17403 PHONE 717-428-0186