With all of the above
mentioned methods for the determination of internal deposit
stress in applied coatings, numerous false assumptions
have masked an understanding of what the most accurate
deposit stress value really is for a given set of conditions.
This needs clarification and correction. The basic questions
to ask are, “What is the actual degree of the deposit
stress and how can the correct value be obtained?”
For
example, in Table 3 and in Figs. 7-9, the deposit stress
values for a given metal coating vary widely with length
of deposition time as the only variable. It is recognized
that increased deposition time causes greater deposit
thickness values. But why are the initial values low,
then reach
a peak, then fall to lower values again? This phenomenon
is observed when determining deposit stress values
by all of the methods referenced in the body of this
paper.
The
thinner deposit values appear to be considerably lower
than the actual value, and the thicker deposit values
appear to be much lower than the actual deposit stress
values
also.
The reasonable conclusion is that only one of the corresponding
deposit stress values for a given coating is close
to the actual value. Logically, it follows that the
deposit stress
actually does not change with plating time as the
only variable, but remains constant. |